For this to work, you would have to sort your coins in descending order, or use reversed(coinList) instead of coinList in the first for loop and vice versa in the second if you would like to sort them forwards:
total = 250
value = 0
coins = []
coinList = [100, 100, 20, 20, 20, 10, 10]
for coin in coinList:
if value + coin <= total:
value += coin
coins.append(coin)
else:
continue
if value >= total:
break
else:
for coin in reversed(coinList):
value += coin
coins.append(coin)
if value >= total:
break
print coins
2
solved Python finding most efficient combination of coins to reach item value