I really suggest you to take a look over the documentation. A simple loop would solve your problem:
a = [1, 2, 3, 4, 5]
results = []
for i in range(len(a)-1):
results.append((a[i]+a[i+1])/2)
print(results)
Output: [1.5, 2.5, 3.5, 4.5]
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solved Very basic Riemann sum in Python