Yes, it’s possible to access the web server from an external network, depending on your current network configuration.
There are two simple solutions I think would suit you.
- Configure your firewall if needed, enable port forwarding in your router settings to forward port 80 to the internal IP of the machine running your XAMPP-server.
- If you’re on a network in which you can’t configure, I recommend checking out ngrok.com, which is a service where you can setup a public URL for your XAMPP-server. Works from any type of network, where you have internet-access, of course.
Note, alternative 2 is good for exposing a development-server, nothing I’d recommend for running a site in production.
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solved Server data accessing from non local network without port forwarding