Assuming that the .txt file contains one word per line, here is a simple solution:
string[] keywords = System.IO.File.ReadAllLines(@"C:\Temp\keywords.txt");
List<string> nomatch = new List<string>();
System.Net.WebClient wc = new System.Net.WebClient();
foreach (string word in keywords)
{
string response = wc.DownloadString("http://www.website.com/search.php?word=" + word);
if (response != null && response.Contains("No matches found"))
nomatch.Add(word);
}
if (nomatch.Count > 0)
System.IO.File.WriteAllLines(@"C:\Temp\nomatch.txt", nomatch.ToArray());
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solved How to search a webpage with keywords from a .txt list? [closed]