MySQLdb (the native driver for MySQL) is not compatible with Python3 yet; but the driver from Oracle for MySQL, called MySQL Connector/Python is compatible with Python 3.
You should use the Oracle driver. django works with both.
Once you have the driver installed, follow the connection section in the documentation.
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solved Django 1.6.1 + MySQL + Apache 2.4.7 on Windows. Is it possible? [closed]