2014-02-18 05:25:38 is a very very specific time to query. You’re only using one of your variables. You probably mean something like this:
$from=$_POST["datefrom"];
$to=$_POST["dateto"];
SELECT * FROM ss_orders where
order_time >= '".$from."' AND
order_time <= '".$to."' limit 60
Also, switch to mysqli or PDO and sanitize those inputs. If this is a public form you could be subjecting yourself to sql injections. mysql_ functions are deprecated.
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solved Mysql & PHP Error [closed]